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  EE Times  High-k, low-k dielectrics hit roadblocks     

 
BURLINGAME, Calif. — This week’s International Interconnect Technology Conference (IITC) brought to mind the famous 1951 science fiction movie classic: The Day the Earth Stood Still.

Or perhaps IITC was more like a new twist on the classic: The Day the Semiconductor Industry Stood Still.

Judging from papers and conversions at the conference here, it was shocking just how little the semiconductor industry has progressed in terms of two critical material technologies—high-k dielectrics and low-k films—for use in next-generation chip designs.

The IITC papers presented a plethora of technology solutions that promise to enable chip designs down to the 32-nm node. But there were whispers in the corridors here among experts that high-k dielectrics and low-k films have separately hit a wall.

There is also a growing sentiment that high refractive-index materials for 193-nm immersion lithography not panning out, thereby implying that immersion will run out of gas at the 32-nm node.

What this further implies is that leading-edge chip makers may resort to a series of technology and economic tradeoffs in future scaling, thereby creating more incremental—or less aggressive—improvements in next-generation chip designs.

For example, there is a growing sentiment that high-k materials for gate stacks in logic devices will not be ready for the 45-nm “half-pitch” node, as many leading semiconductors makers had hoped.

"It won’t be ready," said Hans Stork, senior vice president of silicon technology at Texas Instruments Inc. (Dallas), in a brief interview after a keynote address.

High-k has however made it into production. DRAM makers are using high-k for capacitor formation in memory designs, but the material remains a moving target for gate stacks in logic chips. Delays in high-k could force chip makers to extend conventional but lower-performance silicon dioxide and oxynitrides for the gate stack at the 45-nm node.

High-k dielectric materials were supposed to ride to the rescue by now, improving the electric-field strength in the channel and thus reducing leakage for a given dielectric thickness. The plan was to combine high-k with a metal gate, which would give a superior work function and eliminate the depletion region that forms at the bottom of the polysilicon gate electrode.

Due to their intricate composition, advanced films targeted for 45-nm high-k gate dielectrics—such as hafnium oxide (HfO), hafnium silicate (HfSiO) and hafnium silicate oxynitride (HfSiO/N)—as well as metals like ruthenium, pose a challenge at the film-removal and other process stages.

Like high-k, low-k dielectric films have made it into production to some degree. Low-k materials reduce capacitance and propagation delays within the interconnect layers of a device more effectively than mainstream silicon dioxide insulators, boosting overall chip performance in next-generation designs.

The effectiveness of a low-k material is measured by its dielectric constant. Silicon dioxide has a dielectric constant, or k-value, of 3.9. In 1999, the International Technology Roadmap for Semiconductors called for lower-k materials with values of 2.7 to 2.2. But the complexity of this technology caused the IC industry to push out those targets to 2007 or beyond.

The deployment of low-k has been hampered by integration problems with copper, and by packaging complexities and other factors.

A few leading-edge chip makers implemented the technology at the 90-nm node, reportedly with k values at 2.9 to 3.0. But instead of making a huge leap with low-k, chip makers are now taking incremental steps to extend the technology at the 65-nm node and beyond.

"We are trying to extend the baseline process as long as possible," said Vincent McGahay, senior engineer for the Exploratory Integration Semiconductor Research & Development Center (Hopewell Junction, N.Y.)

In a paper at IITC, IBM described a new version of its carbon-doped silicon oxide technology, dubbed SiCOH, which is said to have a “k” value” of 2.75. IBM’s proprietary film is devised by using chemical vapor deposition (CVD) tools. At present, IBM is using a CVD-based, low-k film with a “k value” of 2.9 to 3.0 as the baseline process for its 90-nm technology.

Some will extend the 2.7 to 2.8 “k-value” films to the 45-nm node and perhaps beyond. This is because low-k has simply hit the wall, said Mahesh Sanganeria, an analyst with RBC Capital Markets Inc. (San Francisco).

“I don’t see [low-k] going beyond 2.5,” he said. “The problem with low-k is the mechanical properties.”

Douglas C.H. Yu, senior director of the Advanced Module Technology Division for silicon foundry giant Taiwan Semiconductor Manufacturing Co. Ltd. (TSMC), was slightly more optimistic about the future scaling of low-k films.

In theory, low-k films based on CVD could be extended down 2.0 in terms of k-value, Yu said. Beyond that, chip makers could be forced to revisit rival technologies—such spin-on, hybrid or air gap—for low-k formation, Yu said.

“We are still leaving our options open,” Yu said, “but I doubt it could be spin-on. However, the hybrid approach is more likely. The drawback is cost. You have more tools and process steps.”

The air-gap approach could be a candidate in the future. At IITC, several chip makers proposed air-gap techniques, including Hitachi, Infineon and Matsushita.

“At one point, everyone has to think about this,” he said. At present, TSMC (Hsinchu) is using a CVD-based low-k film from Applied Materials Inc. (Santa Clara, Calif.), dubbed "Black Diamond."

“For 45 nm, some device manufacturers are talking about 2.7 or 2.5 materials. Some want 2.0 or 2.3 materials,” said Taeko Ikegawa, PECVD technical marketing manager at ASM Japan K.K. (Tokyo), the Japanese subsidiary of Dutch-based equipment maker ASM International N.V.

“At the 32- or 22-nm nodes, we could see a convergence of spin-on and CVD. Air gap is very interesting too,” she said. “But I don’t think that the industry has a clear vision of the 32-nm node.”

One possible way to track the world’s largest producer of low-k-enable chips is to follow the roadmap of ASMI. ASMI is reportedly the main low-k equipment provider for Intel Corp. (Santa Clara, Calif.). Starting at the 90-nm node, Intel has been reportedly using AMSI’s CVD-based low-k film, dubbed "Aurora."

In a paper at IITC, the team of ASMI and Japan’s Semiconductor Leading Edge Technologies Inc. (Selete) described an Aurora-based film with a k value of 2.3 and a high modulus of 7.2 GPa. The technology is geared for the 45-nm node and beyond.